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,, (. 1),,,.., 0. 0.,,, (, ) (. 2).,, Liou [4] Noel [5]., [4, 5].,,,.. 2, ( = 110) 0 = 20.

, [7], : 22, 120..,,.

. 3 Q = 0,1 0 = 15 = 0,55 ( = 105) K.N. Liou [5]. = 50100, Liou 6, (Q = 0,1) (0 = 15). = 020 ( ) Liou,.

. 1., : parhelic circle;

22 parhelion (sundog); 120 parhelion; subparhelic circle,. 2. - (a) 0 = 20, Q = 0,1 () K.N. Liou,. 3. 2D- Q = 0,1 0 = 15 (parhelic circle) 1... //. 2001.. 14. 2.. 116124.

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,,, 20180 [8],, [9]: CaO + SO2 {+2H2O} = CaSO3{*2H2O}, CaSO3*2H2O + 1/2O2 = CaSO4*2H2O.

L = 58, Sum = 71,2 /3 L = 65, Sum = 51,0 /L = 73, Sum = 24,9 /3 L = 82, Sum = 20,8 /L = 92, Sum = 11,4 /. 5. (L),, 60100, [3, 4]. SO2,,, ,.

1...,..,....:, 1991. 256.

2..., :.. ..-...:, 2002. 29.

3...,..,.....:, 1989.

269.

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, 1996.. 237.

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40,.,.. 25 35 /,,.. ,,. ,,,. (Ref), Ref 2000, [4].

7 6,4,.,.. NO, NO2, SO2, CO2, CO,.

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, HYCAL Products Hon- 0,1 C; T 70 +70 C 0,5 C;

eywell Inc., : IH 3602C 1%. 0 100% 7% wd, 0...360 10% M-v, / 0...10% M-115 10 /2 01368 /2 10% 0,4 d 10, - N 300 3 20% -6 (12-) (8- 3 d 200 N 105 3 10% ) NO 0,1 /3 01000 /3 25% NO2 1 /3 01000 /3 25% O3 1 /3 11000 /3 15% SO2 1 /3 02000 /3 25% CO2 - 100 ppm 02000 ppm 20% CO 0,1 /3 0400 /3 20%. - 10, 25 ( 10 3//) 1, 2,. 1. AKB: 1, 2, 3 ; 4 ; 5 - ; 6 4.115.-2 24 220.,,..,.,,,.,,,.,, 220,.,,,,,.

.,, TOR-,,,,,.

1...,..,... TOR- //. 1994.. 7. 8.. 1085.

2...,..,... IBM- //.

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3. 4.115.003..

4...., 1957. 350.

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., [5].

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163.

3...,..,..,.,..,..,..,.. //. 2002.. 15. 11.. 10271030.

4...,..,..,..,..,.., -..,..,.. //. 2003.. 39. 5.. 7790.

5...,..,..,..,..,.., -..,... :.., 1987. 225.

D216O 17504330 ..,..

,,.

E-mail: starikova_e@iao.ru ( D216O).,,,,,,,.

SyMath; (, ), 1750 3200 1; (020), (100) (001);.

, (, - ). :,, ab initio.

, (H216O, H217O, H218O, D216O, D217O, D218O) 1 22 3. (1) (v1v2v3), 2v1 + v2 + 2v3 = n, n = 0, 1, 2,.... (2). D216O. (020) (100),,. (100) (001),,. (020) (001).

H11 H21 HTRI HG = H12 H22 H32. (3) H13 H23 H : 1 (020), 2 (100), 3 (001).,,. :

HG = J2j + gjiJ2jGi /[1+ G0] + J2i {Gj,J2 }, (4) j0 ji xy g u ji+j=1 ij i G = ( 1+(J)J2 -1), (5) z (J) (J) J2;. H12, - (020) (100), :

H12 = f000+ f020J2 + f002(J2+J2). (6) z + (020) (100) f000 H12, 34,24 1 [1].

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:

K %(v1v2v3JKKc) = (7) a V C, K K CV (v1v2v3JKaKc), :

K vv2v3 JKaKc = (8) 1 V C JK V.





VP K v,. = {(020), (100), (001)}.

H13 H23 Hi3 = c001(J+ - J-) + c011(J+(Jz+1 2)+(Jz+1 2)J-) + c201J2(J+ - J-) + + c021(J+(Jz+1)2 -(Jz+1)2J-)+c031(J+(Jz+3 2)3+(Jz+3 2)3J-) + + c013(J+(Jz+1 2)3+(Jz+1 2)3J3) + c211J2(J+(Jz+1 2)), (9) i = 1 2., (020) (001), 011, 021 201, H23, (100) (001), 001, 011, 031, 211, 013.

,, Georg Mellay Bruker IFS 120 HR (., ) 0,015 1 1950.

, Symath,,. 22, 1 (020), (100) (001).

17502000 1, 3 2. 320860 1 (, ) (020)(020), (100)(100) (001)(001), (020) (100), (020)(001) (001)(100),., [1, 2]. D2O,.. [3, 4].

(020), (100) (001) [2, 3],,, J Ka.

J Ka max, c1 J Ka max, c [1, 2] (020) 162 16 9 3850 320 26 18 (100) 184 17 10 4515 330 21 20 (001) 223 19 10 4760 537 30 20 1342 D216O (020), (100) (001).

, 250 32 2, 2 + 3 2, 1 + 2 2,, - 42 22, 52 32, 22 + 3 32.

(020), (100) (001),,. (020). J 13 (020) (010) K = 13, 14..

1. Papineau N., Flaud J.-M., Camy-Peyret C., Guelachvili G. The 22, 1, and 3 bands of D216O. The ground state (000) and the triad of interacting states {(020), (100), (001)} // J. Mol. Spectrosc. 1981.

V. 87. P. 219232.

2. Toth R.A. HDO and D2O low pressure, long path spectra in the 6003100 cm1 region. II. D2O line positions and strengths // J. Mol. Spectrosc. 1999. V. 195. P. 98122.

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